Characterization of historical pigments through imaging techniques, in various bands of the electromagnetic spectrum
Abstract
This paper proposes a proof of concept for the observation using multiband imaging techniques of 63 historical pigments (used from Antiquity to the 20th century). The response of these pigments has been documented at various points of the spectrum by constructing their images, by reflection, transmission, fluorescence, and false color, from the visible (VIS) to its two extremes, ultraviolet (UV) and infrared (IR). The study has been also completed with the radiographic image (RX). Each pigment responds differently in each of the techniques used, depending on its spectral behavior, which generates a unique behavior pattern for each material. The set of techniques used make up a methodology that proposes 11 possible ways of seeing, although it is in their transversal reading and confrontation where more complete results are achieved, th+rough an inductive method based on observation. This is a novel study, which although it has isolated precedents, summarizes for the first time in the form of images, the spectral behavior of such pigments. The results obtained intend, thus, to contribute to the improvement the interpretation of non-invasive imaging techniques applied to pictorial artworks, allowing the preliminary identification of some pigments.
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References
AGUILAR-TÉLLEZ, D. M., RUVALCABA-SIL, J. L., CLAES, P., & GONZÁLEZ-GONZÁLEZ, D. (2014). False color and infrared imaging for the identification of pigments in paintings. MRS Online Proceedings Library (OPL), 1618: 3-15. https://doi.org/10.1557/opl.2014.451
ACCORSI, G. VERRI, M. BOLOG NESI, N. ARMAROLI, C. CLEMENTI, C. MILIANI, A. ROMANI (2009). The exceptional near-infrared luminescence properties of cuprorivaite (Egyptian blue), Chem. Com mun., 3392–3394. https://doi.org/10.1039/b902563d
ALDROVANDI, A., E. BUZZEGOLI, A. KELLER, AND D. KUNZELMAN. (2004). Indagini su Superfici Dipinte Mediante Immagini UV Riflesse in Falso Colore. OPD Restauro: Rivista dell’Opificio delle Pitre Dure e Laboratorio di Resauro di Firenze, 16: 83-87.
ALDROVANDI, A., E. BUZZEGOLI, A. KELLER, AND D. KUNZELMAN. (2005). Investigation of painted surfaces with reflected UV false color technique. In 8th International conference on “Non-destructive investigations and microanalysis for the diagnostics and conservation of the cultural and environmental heritage”, Lecce, Italy, 15–19 May 2005, eds. C. Parisi, G. Buzzanca, and A. Paradisi. Brescia, Italy: Associazione Italiana Prove Non Distruttive Monitoraggio Diagnostic. 3-18.
ALDROVANDI, A.; PICOLLO, M. (1999) Metodi di documentazione e indagini non invasive sui dipinti. Il Prato: Padova.
BONANNO, A., BOZZO, G., STRANGES, F., & SAPIA, P. (2017). La riflettografia infrarossa tra fisica, arte e tecnologia. Il Giornale di Fisica, 1: 27-51. https://doi.org/10.1393/gdf/i2017-10260-5
BRIDGMAN, C. F., AND GIBSON, L. H. (1963). Infrared Luminescence in the Photographic Examination of Paintings and Other Art Objects. Studies in Conservation, 8(3): 77-83. https://doi.org/10.2307/1505133
BURROUGHS, A. (1928). Notes on the principles and process of X-ray examination of painting. Washington D C, Estados Unidos: Smithsonian report for 1927.
CONTI, S., AND A. KELLER. (2010). Il Colore nei Materiali Tessili Antichi: Standard di Riferimento e Caratterizzazione dei Coloranti per Mezzo di Indagini Ottiche. OPD Resatauro: Rivista dell’opificio delle Pietre Dure e Laboratorio di Restauro di Firenze, 20: 57-72.
COSENTINO, A. (2014). Identification of pigments by multispectral imaging; a flowchart method. Heritage Science, 2(1): 1-12. https://link.springer.com/article/10.1186/2050-7445-2-8
COSENTINO, A. (2015). Practical notes on ultraviolet technical photography for art examination. Conservar Património, (21), 53-62. https://www.redalyc.org/pdf/5136/513651366004.pdf
COSENTINO, A. (2016). Infrared technical photography for art examination. e-Preservation science, 13: 1-6.
COSENTINO, A.; STOUT, S. (2014). Photoshop and multispectral imaging for art documentation. e-Preservation Science, 11, 91-98. https://www.academia.edu/download/39236800/5450afd60cf249aa53dabdb8.pdf
DE LA RIE, R.E. (1982). Fluorescence of Paint and Varnish Layers (Part I). Studies in Conservation, 27: 1-7; 65-69; 102-108. https://doi.org/10.1179/sic.1982.27.1.1
DÍAZ, A. (1975). Restauración y Conservación del Arte Pictórico. Madrid, España: ArteRestauro.
DOERNER, M. (2001). Los materiales de pintura y su empleo en el arte. Reverté.
DYER, J., VERRI, G., AND CUPITT, J. (2013). Multispectral Imaging in Reflectance and Photo-induced Luminescence Modes: A User Manual. London: The British Museum
GARGANO, M., LUDWIG, N., & POLDI, G. (2007). A new methodology for comparing IR reflectographic systems. Infrared Physics & Technology, 49(3): 249-253. https://www.sciencedirect.com/science/article/pii/S1350449506000855
GARRIDO, C., y CABRERA, J.Mª. (1983). “La Fragua de Vulcano”. Estudio técnico y algunas consideraciones sobre los materiales y métodos del XVII. Boletín del Museo del Prado, 4(11): 79-95.
GETTENS, R. J. FELLER, R; CHASE, W.T. (1993). Vermilion and Cinnabar. En Ashok Roy. (Ed), Artists’ Pigments. A handbook of their history and characteristics. . Londres, Reino Unido: Archetype Publications. 2: 159-182.
GETTENS, R. J.; WEST FITZHUNG, E. (1993). Malachite and Green Verditer. En Ashok Roy. (Ed), Artists’ Pigments. A handbook of their history and characteristics. Londres, Reino Unido: Archetype Publications. 2: 183-202.
GETTENS, R.J.; KÜHN, H.; CHASE, W.T. (1993). Lead White. En Ashok Roy. (Ed), Artists’ Pigments. A handbook of their history and characteristics. Londres, Reino Unido: Archetype Publications. 2: 67-82.
GRIFONI, E., BRIGANTI, L., MARRAS, L., ORSINI, S., COLOMBINI, M. P., LEGNAIOLI, S., PALLESCHI, V. (2015). The chemical-physical knowledge before the restoration: the case of “The Plague in Lucca”, a masterpiece of Lorenzo Viani (1882–1936). Heritage Science, 3(1): 26. http://doi.org/10.1186/s40494-015-0055-0
HERRERO-CORTELL, M. Á. (2019). Procedimientos técnicos, soportes y materiales utilizados en los obradores pictóricos de la corona de aragón (s. XV- XVI). Una aproximación a través del paradigma valenciano. Lleida: Universitat de Lleida.
HERRERO-CORTELL, M. Á., CREUS, M. R., ARTONI, P., & SANCHIS, I. P. (2018). Multi-band technical imaging in the research of the execution of paintings. The case study of the portrait of Carlos IV, by Francisco de Goya. Ge-conservación, 14: 5-15. https://doi.org/10.37558/gec.v14i1.583
HERRERO-CORTELL, M., ARTONI, P., & RAÏCH, M. (2020). Transmitted light imaging in VIS and IR, in the study of paintings: a brief report on the behavior of the main historical pigments. Cultura e Scienza del Colore-Color Culture and Science, 12(02): 79-88. https://doi.org/10.23738/CCSJ.120210
HERRERO-CORTELL, M. Á; ARTONI, P.M CREUS, M. R., ALIAGA, J. PUIG, I. 2021). Observando a través de los estratos: fotografía infrarroja transmitida (IRT) aplicada al estudio técnico y documental de pinturas sobre lienzo. Ge-conservación, (19(1): 62-73. https://doi.org/10.37558/gec.v19i1.840
HOURS-MIEDAN, M. (1964). Les secrets des chefs-d`oeuvre. L`oeuvre d`art est matière avant d`être message. Paris, Francia: Èditions Robert Laffont.
KIRBY, J.; VAN BOMMEL, M.; VERHECKEN, A. (2014) Natural Colorants for Dyeing and Lake Pigments. Practical Recipes and their Historical Sources. London: Archetype.
KELLER, A. T., LENZ, R., ARTESANI, A., MOSCA, S., COMELLI, D., & NEVIN, A. (2019). Exploring the ultraviolet induced infrared luminescence of titanium white pigments. Conservation 360º, 1:201-232. https://monografias.editorial.upv.es/index.php/con_360/article/view/79
LANG, J., & MIDDLETON, A. (1997). Radiology of Cultural Material. Londres: Elsevier Butterworh-Heinemann
MADRID, J.A. (2010). Catálogo radiográfico del servicio de rayos X del Laboratorio de Documentación y Registro. Arché, 10: 87-98. http://hdl.handle.net/10251/85227
MADRID, J.A. (2014). Dos décadas de inspección radiográfica en España: retrospectiva y horizontes en un contexto de cambio tecnológico. Intervención. Revista Internacional de Conservación, Restauración y Museología, 85: 85-93. https://www.redalyc.org/comocitar.oa?id=355632777011
MOON, T., SCHILLING, M. R., THIRKETTLE, S. (1992). A note on the use of false-color infrared photography in conservation. Studies in Conservation, 37 (1):42-52 https://doi.org/10.2307/1506436
MUCCHI, L., Y BERTUZZI, A. (1983). Nella profondità dei dipinti. La radiografia nell`indagine pittorica. Milan: Ed. Electa.
PICOLLO, M.; FUSTER LÓPEZ, L. STOLS-WITLOX, M. (2020). UV-Vis Luminescence imaging techniques/ Técnicas de imagen de luminiscencia UV-Vis. Editorial Universitat Politècnica de València. http://hdl.handle.net/10251/138517
POLDI, G.; VILLA, G.. (2006). Dalla conservazione alla storia dell’arte: riflettografia e analisi non invasive per lo studio dei dipinti. Edizioni della Normale, 3.
RAÏCH, M.; ARTONI, P.; HERRERO-CORTELL; M.; LA BELLA, A.; RICCI, M.L; HERNÁNDEZ, A. (2019). “Riconoscere dal colore. Pigmenti e coloranti dell’età moderna nell’analisi multibanda dei dipinti: uno strumento visivo per gli storici dell’arte e i conservatori”, in Colore e Colorimetria. Contributi multidisciplinari, 120-127.
ROGGE, C; LOUGH, K. (2016). Fluorescence Fails: Analysis of UVA-Induced Visible Fluorescence and False-Color Reflected UVA Images of Tintype Varnishes Do Not Discriminate Between Varnish Materials. Journal of the American Institute for Conservation, 55(2): 138-147. https://doi.org/10.1080/01971360.2016.1155813
RORIMER, J.J. (1931). Ultra-violet rays and their use in the examination of works of art. New York: The Metropolitan Museum of Art.
THOURY, M., DELANEY, J.K., RIE, E.R., PALMER, M., MORALES, K., AND KRUEGER, J. (2011). Near-infrared luminescence of cadmium pigments: in situ identification and mapping in paintings. Appl Spectrosc, 65(8): 939-951.
VANPAEMEL, G. (2010). X-rays and Old Masters. The Art of the Scientific Connoisseur. Endeavour 34(2): 69-74.
VERRI, G. (2009). The spatially resolved characterisation of Egyptian blue, Han blue and Han purple by photo-induced luminescence digital imaging. Analytical Bioanalytical Chemistry, 394(4): 1011-1021.
WARDA, J., (ed.) (2011). The AIC guide to digital photography and conservation documentation. Washington, DC: Foundation of the American Institute for Conservation of Historic and Artistic Works.
WEST FITZHUNG, E. (1985). Red Lead and Minium. En Robert L. Feller. (Ed), Artists’ Pigments. A handbook of their history and characteristics, Londres, Reino Unido: Archetype Publications. 1: 109-139.
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